Kinsella, Michael and Duggan, Patrick G. and Muldoon, Jimmy and Eccles, Kevin S. and Lawrence, Simon E. and Lennon, Claire M. (2011) Synthesis and NMR binding studies towards rational design of a series of electron-withdrawing diamide receptors/organocatalysts. European Journal of Organic Chemistry (6). pp. 1125-1132. ISSN 1434-193X
Full text not available from this repository. (Request a copy)Abstract
A related series of bisamides have been evaluated for rational correlation between anion complexation and organocatalysis: remarkable enhancement of hydrogen bonding to anions was observed along with significant increases in catalytic activity in the Baylis-Hillman reaction. In addition, X-ray crystallography showed a large degree of pre-organisation was observed in one receptor by incorporation of bis(trifluoromethyl)aniline groups along with a thioamide functionality. A novel bifunctional amide/N-acylsulfonamide within the series gave the best catalytic profile.
Item Type: | Article |
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Uncontrolled Keywords: | /dk/atira/pure/subjectarea/asjc/1600/1606 |
Departments or Groups: | |
Depositing User: | Admin SSL |
Date Deposited: | 19 Oct 2022 23:06 |
Last Modified: | 07 Jun 2023 18:44 |
URI: | http://repository-testing.wit.ie/id/eprint/4100 |
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